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Aromatic compounds bearing one or more strong electron-withdrawing substituents in addition to a leaving group can sometimes bear nucleophilic substitution in place of electrophilic substitution. The normal mechanisms of $mathrm S _ mathrm N two$ and $mathrm S _ mathrm N 1$ reactions are impossible because of the $s p^ two $ -hybridization with the carbons of a benzene ring, but a system that involves nucleophilic addition followed by elimination, called $S_ mathrm N mathrm Ar $ (nucleophilic aromatic substitution), is possible.

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